I recently visited a brewery and they have their boilers covered but with a chimney to outside to allow boil off.
So does this allow enough of a boil off for DMS to evaporate out?
Surely some liquid condenses on the cover around the chimney open and drops back in?
Exactly what jomebrew said.
Steam stacks for brewhouses have features to aid evaporation. They are typically tall, which draws the moisture up quickly. They may also have misting nozzles in them or a fan to pull steam. Steam will want to go from the hottest to the coolest place as fast as it can.
To prevent condensate, most have a crook in the stack. This offset is below the point where the steam might condense and rain back down.The condensate then travels down the side of the stack and is collected in a ring just above the kettle. There's a drain for it that goes to the floor under the brewhouse.
Properly designed, steam won't escape through the kettle manway door. There will be an obvious vortex of air being pulled in.
If you collect this condensate in the first 20 minutes of the boil, it will have a distinctly canned corn flavor and smell. It diminishes as DMS is distilled out.